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Strategic position and development prospects of nuclear energy in China

SHEN Wenquan

《能源前沿（英文）》 2007年 第1卷 第2期   页码 125-128 doi: 10.1007/s11708-007-0015-9

摘要： By analyzing the challenges of China s energy supply, an excellent perspective of nuclear power development in the country has been described. Taking into account the near-, mid-, and long-term development requirements, a comprehensive, coordinated and sustainable nuclear power program is proposed. Thus, our national nuclear industry can not only catch up with the world s advanced level in proper time, but also possess enough stamina for sustainability.

关键词： development     excellent perspective     long-term development     comprehensive     national    

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Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy

《化学科学与工程前沿（英文）》   页码 1616-1622 doi: 10.1007/s11705-022-2183-x

摘要： Adsorptive separation of acetylene/carbon dioxide mixtures by porous materials is an important and challenging task due to their similar sizes and physical properties. Here, remarkable acetylene/carbon dioxide separation featuring a high dynamic breakthrough capacity for acetylene (4.3 mmol·g–1) as well as an ultralow acetylene regeneration energy (29.5 kJ·mol–1) was achieved with the novel TiF62–-pillared material ZU-100 (TIFSIX-bpy-Ni). Construction of a pore structure with abundant TiF62– anion sites and pores with appropriate sizes enabled formation of acetylene clusters through hydrogen bonds and intermolecular interactions, which afforded a high acetylene capacity (8.3 mmol·g–1) and high acetylene/carbon dioxide uptake ratio (1.9) at 298 K and 1 bar. Moreover, the NbO52– anion-pillared material ZU-61 investigated for separation of acetylene/carbon dioxide. In addition, breakthrough experiments were also conducted to further confirm the excellent dynamic acetylene/carbon dioxide separation performance of ZU-100.

关键词： adsorption     acetylene/carbon dioxide separation     dynamic capacity     anion-pillared hybrid material    

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A new perspective in pyroptosis: lifting the veil on GSDMA activation

《医学前沿（英文）》 2023年 第17卷 第3期   页码 581-583 doi: 10.1007/s11684-022-0971-9

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INDIAN PERSPECTIVE: SUSTAINABILITY OF BT COTTON IS A MATTER OF CONCERN NOW!

《农业科学与工程前沿（英文）》 2022年 第9卷 第1期   页码 146-149 doi: 10.15302/J-FASE-2021415

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multifunctional polypyrrole/cellulose nanofiber composite films with outstanding photothermal effect, excellent

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1028-1037 doi: 10.1007/s11705-022-2251-2

摘要： Electrodes that combine energy storage with mechanical and photothermal performance are necessary for efficient development and use of flexible energy storage and conversion devices. In this study, the flexible, ultrathin, and multifunctional polypyrrole/cellulose nanofiber composite films were fabricated via a one-step “soak and polymerization” method. The dense sandwich structure and strong interfacial interaction endowed polypyrrole/cellulose nanofiber composite films with excellent flexibility, outstanding mechanical strength, and desired toughness. Interestingly, the polypyrrole/cellulose nanofiber composite film electrodes with quaternary amine functionalized cellulose nanofiber had the highest specific mass capacitance (392.90 F∙g–1) and specific areal capacitance (3.32 F∙cm–2) than the electrodes with unmodified and carboxyl functionalized cellulose nanofibers. Further, the polypyrrole/cellulose nanofiber composite films with sandwich structure had excellent photothermal conversion properties. This study demonstrated a feasible and versatile method for preparing of multifunctional composite films, having promising applications in various energy storage fields.

关键词： cellulose nanofiber     electrochemical     photothermal conversion     polypyrrole    

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Co anchored on porphyrinic triazine-based frameworks with excellent biocompatibility for conversion of

《化学科学与工程前沿（英文）》 2022年 第16卷 第12期   页码 1761-1771 doi: 10.1007/s11705-022-2195-6

摘要： Microbial electrosynthesis is a promising alternative to directly convert CO2 into long-chain compounds by coupling inorganic electrocatalysis with biosynthetic systems. However, problems arose that the conventional electrocatalysts for hydrogen evolution may produce extensive by-products of reactive oxygen species and cause severe metal leaching, both of which induce strong toxicity toward microorganisms. Moreover, poor stability of electrocatalysts cannot be qualified for long-term operation. These problems may result in poor biocompatibility between electrocatalysts and microorganisms. To solve the bottleneck problem, Co anchored on porphyrinic triazine-based frameworks was synthesized as the electrocatalyst for hydrogen evolution and further coupled with Cupriavidus necator H16. It showed high selectivity for a four-electron pathway of oxygen reduction reaction and low production of reactive oxygen species, owing to the synergistic effect of Co–Nx modulating the charge distribution and adsorption energy of intermediates. Additionally, low metal leaching and excellent stability were observed, which may be attributed to low content of Co and the stabilizing effect of metalloporphyrins. Hence, the electrocatalyst exhibited excellent biocompatibility. Finally, the microbial electrosynthesis system equipped with the electrocatalyst successfully converted CO2 to poly-β-hydroxybutyrate. This work drew up a novel strategy for enhancing the biocompatibility of electrocatalysts in microbial electrosynthesis system.

关键词： microbial electrosynthesis     hydrogen evolution reaction     metalloporphyrins     biocompatibility     CO2 conversion    

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Applying an Integrated Systems Perspective to the Management of Engineering Projects

Simon P. Philbin

《工程管理前沿（英文）》 2015年 第2卷 第1期   页码 19-30 doi: 10.15302/J-FEM-2015004

摘要： Engineering projects can be subject to significant complexity, which may result in a number of issues and challenges that need to be addressed throughout the project life-cycle. Traditionally projects have been viewed according to the so called “iron triangle,” i. e., achievement of project milestones according to schedule, cost and quality targets. While these targets are fundamentally important to the performance of engineering projects, it is possible to view projects on a systemic level in order to allow an adequate focus on all the underpinning factors that have the potential to influence the performance of projects. Consequently, a management framework has been developed that is based on an integrated systems perspective of engineering projects, where the performance of projects is a function of six contributing sub-systems that are: process, technology, resources, knowledge, culture and impact.

关键词： integrated systems perspective     engineering projects     management    

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Aerobic granulation of pure bacterial strain

ADAV Sunil S., LEE Duu-Jong

《环境科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 461-467 doi: 10.1007/s11783-008-0066-0

摘要： The objective of this study is to cultivate aerobic granules by pure bacterial strain, , in a sequencing batch reactor. Stable granules sized 2.0–2.2 mm were formed in the reactor after a five-week cultivation. These granules exhibited excellent settling attributes, and degraded phenol at rates of 1.49 and 1.19 g phenol/(g VSS·d) at 250 and 1500 mg/L of phenol concentration, respectively. Confocal laser scanning microscopic test results show that was distributed over the initial small aggregates, and the outer edge of the granule was away from the core regime in the following stage.

关键词： following     excellent settling     phenol/     sequencing     microscopic    

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Ni particles with phosphorus and adjacent defects catalyze 1,5-dinitronaphthalene hydrogenation with excellent

Wei Xiong, Susu Zhou, Zeyong Zhao, Fang Hao, Zhihui Cai, Pingle Liu, Hailiang Zhang, Hean Luo

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 998-1007 doi: 10.1007/s11705-020-1994-x

摘要： This work proposes a modified activated carbon support, with defects and heteroatoms (N,P-ACs) by nitrogen and phosphorus doping to load non-noble nickel to catalyze aromatic compound hydrogenation. The Ni/N,P-ACs-900 (prepared at 900 °C) showed promising catalytic activity in liquid-phase 1,5-dinitronaphthalene hydrogenation with a 1,5-diaminonaphthalene yield of 95.8% under the mild condition of 100 °C, which is comparable to the commercial Pd/C catalyst. The nitrogen species were burned off at 900 °C, causing more defects for nickel metal loading, facilitating the interaction between the supports and the nickel metal, and resulting in highly dispersed metal particles. The computational study of the nickel binding energy has been conducted using density functional theory. It exhibits that the defects formed by heteroatom doping are beneficial to nickel anchoring and deposition to form highly uniform nickel particles. The phosphorus species in combination with the defects are suitable for H adsorption and dissociation. These results reveal that the heteroatomic doping on the active carbon shows significant effects in the hydrogenation of the liquid-phase aromatic compounds. These findings could provide a promising route for the rational design of aromatic compound hydrogenation catalysts to significantly decrease the cost by instead using noble metal catalysts in the industry.

关键词： nitrogen and phosphorus doping     non-noble nickel catalyst     aromatic compounds hydrogenation    

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Comments on the development of blockchain technology from the perspective of patent analysis

Wenhong LI, Chunxiao FU, Deli CHENG

《工程管理前沿（英文）》 2020年 第7卷 第4期   页码 615-617 doi: 10.1007/s42524-020-0101-9

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Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1537-1549 doi: 10.1007/s11705-021-2094-2

摘要： Human health is deteriorating due to the effluent containing heavy metal ions and organic dyes. Hence, photoreduction of Cr(VI) to Cr(III) and degradation of rhodamine B (RhB) using a novel photocatalyst is particularly important. In this work, h-BN/NiS2/NiS composites were prepared via a simple solvothermal method and a double Z-scheme heterojunction was constructed for efficiently removing RhB and Cr(VI). The 7 wt-% h-BN/NiS2/NiS composites were characterized via a larger specific surface area (15.12 m2·g–1), stronger light absorption capacity, excellent chemical stability, and high yield of electrons and holes. The experimental result indicated that the photoreduction efficiency of the 7 wt-% h-BN/NiS2/NiS photocatalyst achieved 98.5% for Cr(VI) after 120 min, which was about 3 times higher than that of NiS2/NiS (34%). However, the removal rate of RhB by the 7 wt-% h-BN/NiS2/NiS photocatalyst reached 80%. This is due to the double Z-scheme heterojunction formed between NiS2/NiS and h-BN, which improved the charge separation efficiency and transmission efficiency. Besides, the influence of diverse photogenerated electron and hole scavengers upon the photoreduction of Cr(VI) was studied, the results indicated that graphene-like h-BN promoted transportation of photoinduced charges on the surface of the h-BN/NiS2/NiS photocatalyst via the interfacial effects.

关键词： graphene-like h-BN     h-BN/NiS2/NiS composites     photocatalysis     Cr(VI) reduction     degradation of RhB    

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Contributions in renewable energy systems: A perspective from the latest publications of FCSE

Xiaowen Zhu, Di Xu, Jing-Kang Wang

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 632-635 doi: 10.1007/s11705-019-1904-2

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Photoaging mechanism of microplastics: a perspective on the effect of dissolved organic matter in natural

《环境科学与工程前沿（英文）》 2023年 第17卷 第11期 doi: 10.1007/s11783-023-1743-8

摘要：

● Microplastics (MPs) undergo photoaging in natural water under light irradiation.

关键词： Microplastics     Photoaging     Dissolved organic matter     ROS generation    

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A PDEM-based perspective to engineering reliability: From structures to lifeline networks

Jie LI

《结构与土木工程前沿（英文）》 2020年 第14卷 第5期   页码 1056-1065 doi: 10.1007/s11709-020-0636-1

摘要： Research of reliability of engineering structures has experienced a developing history for more than 90 years. However, the problem of how to resolve the global reliability of structural systems still remains open, especially the problem of the combinatorial explosion and the challenge of correlation between failure modes. Benefiting from the research of probability density evolution theory in recent years, the physics-based system reliability researches open a new way for bypassing this dilemma. The present paper introduces the theoretical foundation of probability density evolution method in view of a broad background, whereby a probability density evolution equation for probability dissipative system is deduced. In conjunction of physical equations and structural failure criteria, a general engineering reliability analysis frame is then presented. For illustrative purposes, several cases are studied which prove the value of the proposed engineering reliability analysis method.

关键词： PDEM     reliability     structure     lifeline networks    

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Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells

Gang WU

《能源前沿（英文）》 2017年 第11卷 第3期   页码 286-298 doi: 10.1007/s11708-017-0477-3

摘要： To significantly reduce the cost of proton exchange membrane fuel cells, platinum-group metal (PGM)-free cathode catalysts are highly desirable. Current M-N-C (M: Fe, Co or Mn) catalysts are considered the most promising due to their encouraging performance. The challenge thus has been their stability under acidic conditions, which has hindered their use for any practical applications. In this review, based on the author’s research experience in the field for more than 10 years, current challenges and possible solutions to overcome these problems were discussed. The current Edisonian approach (i.e., trial and error) to developing PGM-free catalysts has been ineffective in achieving revolutionary breakthroughs. Novel synthesis techniques based on a more methodological approach will enable atomic control and allow us to achieve optimal electronic and geometric structures for active sites uniformly dispersed within the 3D architectures. Structural and chemical controlled precursors such as metal-organic frameworks are highly desirable for making catalysts with an increased density of active sites and strengthening local bonding structures among N, C and metals. Advanced electrochemical and physical characterization, such as electron microscopy and X-ray absorption spectroscopy should be combined with first principle density functional theory (DFT) calculations to fully elucidate the active site structures.

关键词： oxygen reduction     fuel cells     cathode     nonprecious metal catalysts     carbon nanocomposites    

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标题 作者 时间 类型 操作

Strategic position and development prospects of nuclear energy in China

SHEN Wenquan

期刊论文

Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy

期刊论文

A new perspective in pyroptosis: lifting the veil on GSDMA activation

期刊论文

INDIAN PERSPECTIVE: SUSTAINABILITY OF BT COTTON IS A MATTER OF CONCERN NOW!

期刊论文

multifunctional polypyrrole/cellulose nanofiber composite films with outstanding photothermal effect, excellent

期刊论文

Co anchored on porphyrinic triazine-based frameworks with excellent biocompatibility for conversion of

期刊论文

Applying an Integrated Systems Perspective to the Management of Engineering Projects

Simon P. Philbin

期刊论文

Aerobic granulation of pure bacterial strain

ADAV Sunil S., LEE Duu-Jong

期刊论文

Ni particles with phosphorus and adjacent defects catalyze 1,5-dinitronaphthalene hydrogenation with excellent

Wei Xiong, Susu Zhou, Zeyong Zhao, Fang Hao, Zhihui Cai, Pingle Liu, Hailiang Zhang, Hean Luo

期刊论文

Comments on the development of blockchain technology from the perspective of patent analysis

Wenhong LI, Chunxiao FU, Deli CHENG

期刊论文

Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance

期刊论文

Contributions in renewable energy systems: A perspective from the latest publications of FCSE

Xiaowen Zhu, Di Xu, Jing-Kang Wang

期刊论文

Photoaging mechanism of microplastics: a perspective on the effect of dissolved organic matter in natural

期刊论文

A PDEM-based perspective to engineering reliability: From structures to lifeline networks

Jie LI

期刊论文

Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells

Gang WU

期刊论文